About: Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation

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About: Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation Goto Sponge NotDistinct Permalink

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description	article (en) wetenschappelijk artikel (nl) article scientifique publié en 2008 (fr) наукова стаття, опублікована в липні 2008 (uk) im Jahr 2008 veröffentlichter wissenschaftlicher Artikel (de)
publication date	wds:Q59203530-426ECAC7-8ED0-47D8-B845-43338872B278
publication date	2008-01-01 00:00:00Z (xsd:dateTime)
language of work or name	wds:Q59203530-8E60B268-7D9B-43BF-A297-F375BE6F675C
language of work or name	English
author name string	wds:Q59203530-9D4BC31E-5540-43B9-86CD-DC4320776ADD
author name string	Sebastian Rendler
rdfs:label	Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation (en) Conclusive Evidence for an SN2-Si Mechanism in the B (nl)
skos:prefLabel	Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation (en) Conclusive Evidence for an SN2-Si Mechanism in the B (nl)
name	Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation (en) Conclusive Evidence for an SN2-Si Mechanism in the B (nl)
author	wds:Q59203530-1EFE7865-249B-4E02-831E-E672E145AF51
author	Martin Oestreich
title	wds:Q59203530-2C0DA8DD-55AB-4006-8502-490D9C9C0A1A
title	Conclusive evidence for an S(N)2-Si mechanism in the B(C6F5)3-catalyzed hydrosilylation of carbonyl compounds: implications for the related hydrogenation (en)
page(s)	wds:Q59203530-FDF87366-AECD-4125-B8FA-A748D1E11ED9
page(s)	5997-6000
instance of	wds:Q59203530-BBEEDB66-D973-49FC-83C9-0B6ABE0856DC
instance of	scholarly article
main subject	wds:Q59203530-07D71249-E626-4589-85A9-E752C19F4AF6
main subject	general chemistry
PubMed ID	wds:Q59203530-26BEC895-620C-4DCC-934E-952CFFFBA7BC
PubMed ID	http://rdf.ncbi.nlm.nih.gov/pubchem/reference/18613156
PubMed ID	18613156
published in	wds:Q59203530-C2D9345E-40FE-410C-A875-ED586D551172
published in	Angewandte Chemie International Edition
issue	wds:Q59203530-1E57A14E-116A-4340-8689-9FEDE1687594
volume	wds:Q59203530-267C8457-BBC0-4070-8193-B47685B4E52D
issue	32
volume	47
DOI	wds:Q59203530-FC6F996C-7FA0-4041-B46D-E5B5FDB46097
DOI	http://dx.doi.org/10.1002/ANIE.200801675
DOI	10.1002/ANIE.200801675
Fatcat ID	wds:Q59203530-3489808A-C56A-4311-9D33-7DD195BCBBD0
Fatcat ID	release_6lsfwgy7rvg4roalkrh7wjq4vi
is about of	https://www.wikidata.org/wiki/Special:EntityData/Q59203530
is cites work of	Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More Superelectrophilic intermediates in nitrogen-directed aromatic borylation Expanding Water/Base Tolerant Frustrated Lewis Pair Chemistry to Alkylamines Enables Broad Scope Reductive Aminations Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations A unified survey of Si-H and H-H bond activation catalysed by electron-deficient boranes Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes Direct observation of a borane-silane complex involved in frustrated Lewis-pair-mediated hydrosilylations Transfer Hydrosilylation. Formal SiH4 chemistry using stable and easy-to-handle surrogates. B(C6F5)3-catalyzed transfer hydrogenation of imines and related heteroarenes using cyclohexa-1,4-dienes as a dihydrogen source. 3-Silylated cyclohexa-1,4-dienes as precursors for gaseous hydrosilanes: the B(C6 F5)3-catalyzed transfer hydrosilylation of alkenes. Synthesis of a Pentacene-Type Silaborin via Double Dehydrogenative Cyclization of 1,4-Diboryl-2,5-disilylbenzene. B(C6 F5 )3 -Catalyzed Cascade Reduction of Pyridines. Metal-free transfer hydrogenation of olefins via dehydrocoupling catalysis Phosphorus Lewis acids: emerging reactivity and applications in catalysis Fundamental and Applied Properties of Borocations Boron-Catalyzed Regioselective Deoxygenation of Terminal 1,2-Diols to 2-Alkanols Enabled by the Strategic Formation of a Cyclic Siloxane Intermediate. N-Methyl-Benzothiazolium Salts as Carbon Lewis Acids for Si-H σ-Bond Activation and Catalytic (De)hydrosilylation Catalytic Dearomatization of N-Heteroarenes with Silicon and Boron Compounds The Propargyl Rearrangement to Functionalised Allyl-Boron and Borocation Compounds. Reductive Dehydrogenation of a Stannane via Multiple Sn-H Activation by Frustrated Lewis Pairs. Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound Σ- versus π-activation of alkynyl benzoates using B(C₆F₅)₃. Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex. A constellation of deuterium-labeled silanes as a simple mechanistic probe not requiring absolute configuration determination. Hydrosilylation of RN=CH Imino-Substituted Pyridines without a Catalyst. Lewis Base Activation of Lewis Acids - Group 13. In Situ Generation and Reaction of Borenium Ions On the concept of frustrated Lewis pairs Mechanism of the cooperative Si-H bond activation at Ru-S bonds. Chemoselective conversion of biologically sourced polyols into chiral synthons A Tale of Two Elements: The Lewis Acidity/Basicity Umpolung of Boron and Phosphorus B(C6 F5 )3 -Catalyzed Selective Chlorination of Hydrosilanes. Base-catalyzed hydrosilylation of ketones and esters and insight into the mechanism. Catalytic Synthesis of Oligosiloxanes Mediated by an Air Stable Catalyst, (C6F5)3B(OH2) Illuminating the mechanism of the borane-catalyzed hydrosilylation of imines with both an axially chiral borane and silane. Intramolecular Activation of C-O Bond by an o-Boryl Group in o-(Alkoxysilyl)(diarylboryl)benzenes Direct Mannich-Type Reactions Promoted by Frustrated Lewis Acid/Brønsted Base Catalysts Si-H bond activation: bridging Lewis acid catalysis with Brookhart's iridium(III) pincer complex and B(C6F5)3. Group 6 Transition-Metal/Boron Frustrated Lewis Pair Templates Activate N2 and Allow its Facile Borylation and Silylation. Heterolytic Si-H Bond Cleavage at a Molybdenum-Oxido-Based Lewis Pair. Borane catalysed ring opening and closing cascades of furans leading to silicon functionalized synthetic intermediates Elektrophile aromatische Substitution mit Siliciumelektrophilen: die katalytische Friedel-Crafts-C-H-Silylierung Diverse Catalytic Systems and Mechanistic Pathways for Hydrosilylative Reduction of CO2 Chemoselective Silylative Reduction of Conjugated Nitriles under Metal-Free Catalytic Conditions: β-Silyl Amines and Enamines. Frustrated Lewis pairs: a metal-free landmark An Axially Chiral, Electron-Deficient Borane: Synthesis, Coordination Chemistry, Lewis Acidity, and Reactivity B(C6 F5 )3 -Catalyzed Chemoselective Defunctionalization of Ether-Containing Primary Alkyl Tosylates with Hydrosilanes. Borinic Acid Catalysed Reduction of Tertiary Amides with Hydrosilanes: A Mild and Chemoselective Synthesis of Amines. B(C6F5)3-katalysierte chemoselektive Defunktionalisierung von etherhaltigen primären Alkyltosylaten mit Hydrosilanen B(C6 F5 )3 -Catalyzed Ring Opening and Isomerization of Unactivated Cyclopropanes. Late-stage chemoselective functional-group manipulation of bioactive natural products with super-electrophilic silylium ions. B(C6F5)3-Catalyzed Reduction of Aromatic and Aliphatic Nitro Groups with Hydrosilanes Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes. Hydridosilylamido complexes of Ta and Mo isolobal with Berry's zirconocenes: syntheses, β-Si-H agostic interactions, catalytic hydrosilylation, and insight into mechanism. A model for C–F activation by electrophilic phosphonium cations Eine Geschichte über zwei Elemente: die Umpolung der Lewis-Acidität/Basizität von Bor und Phosphor Fifty Years of Hydrosilylation in Polymer Science: A Review of Current Trends of Low-Cost Transition-Metal and Metal-Free Catalysts, Non-Thermally Triggered Hydrosilylation Reactions, and Industrial Applications

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