About: A Cyclization-Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold(I)-Aminocarbene Complexes

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About: A Cyclization-Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold(I)-Aminocarbene Complexes Goto Sponge NotDistinct Permalink

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scientific article published on 07 July 2014

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rdf:type	Item
description	wetenschappelijk artikel (nl) наукова стаття, опублікована в липні 2014 (uk) article scientifique publié en 2014 (fr) im Juli 2014 veröffentlichter wissenschaftlicher Artikel (de) scientific article published on 07 July 2014 (en) artículu científicu espublizáu en xunetu de 2014 (ast)
publication date	wds:Q57006669-591BD6E3-1343-48EA-9292-0B43F87854B9
publication date	2014-07-07 00:00:00Z (xsd:dateTime)
language of work or name	wds:Q57006669-534215FB-AED2-4FBB-B106-F933928BEDBB
language of work or name	English
cites work	wds:Q57006669-03EDF0C7-ED87-4B93-A177-B64BC6C87DAF wds:Q57006669-0832F8B0-AF4B-428F-AEB6-564973AA869A wds:Q57006669-0CAD7D2D-BBA3-4D60-B312-F85A791BA638 wds:Q57006669-0F2A7695-8221-45E6-AE72-9C2C2D41AC2E wds:Q57006669-1033380F-B711-46E5-BE83-5EABAF493C8F wds:Q57006669-13ECD93B-C319-4E8A-82C9-BB1C23BB7027 wds:Q57006669-18B35EA0-F646-4CEC-A0C1-857EB1179BE0 wds:Q57006669-1C2E2D41-B51E-4765-9261-49B868BE0B01 wds:Q57006669-1EE0E0A5-A26D-4E5D-B58B-675A41D8144A wds:Q57006669-24AD0A7A-1C20-4405-ADAE-6878AAEEE3B8 wds:Q57006669-33664E2F-54D7-48E3-B411-D89397764E0E wds:Q57006669-3860C0C8-4459-46B0-9868-FA5E8EFFAE41 wds:Q57006669-39BD617C-0D5D-4207-A378-52799633F86F wds:Q57006669-3E563F0E-304E-4110-B8F0-B114E79EB66D wds:Q57006669-5384B9D6-07C6-4B93-AE05-49EB4E9BB063 wds:Q57006669-792C9233-C9A5-4331-80CC-63F4F0C83843 wds:Q57006669-82C250AC-73F7-42CA-B59B-6BEE47A8E56D wds:Q57006669-969AC566-6C27-43B9-8619-F94717A10CFC wds:Q57006669-979EA6A2-89B2-4CEE-81C8-9BDDD685AA64 wds:Q57006669-A3F6939E-E826-4C62-922A-65103149C777 wds:Q57006669-A4E473CC-A90C-4576-A582-EA9EC50B500D wds:Q57006669-AA641649-F368-44D5-BF1E-9C12DA39D722 wds:Q57006669-AE783887-4049-4D97-8590-83A0644D476B wds:Q57006669-B1BE0C44-56A7-4EAE-AD27-C39C99565AB8 wds:Q57006669-B204D6B9-E94A-4FA4-A9A3-B40B73024A65 wds:Q57006669-B786DEC3-11DA-494E-8A0C-888975DB9F2F wds:Q57006669-BE84EEF8-9955-4FAB-A5EA-78A31BF53300 wds:Q57006669-C10036B6-09B1-4340-856C-993644196223 wds:Q57006669-DE3ACA69-AB6C-4910-B302-417DF4A84044 wds:Q57006669-E1CF308E-5CFA-49B3-B65A-D3F09ACCC663 wds:Q57006669-E633A47B-03BD-4D02-9733-A255760C024B
cites work	Anticancer and antimicrobial metallopharmaceutical agents based on palladium, gold, and silver N-heterocyclic carbene complexes. Pyridine substituted N-heterocyclic carbene ligands as supports for Au(I)-Ag(I) interactions: formation of a chiral coordination polymer Gold compounds as therapeutic agents for human diseases Cationic, linear Au(I) N-heterocyclic carbene complexes: synthesis, structure and anti-mitochondrial activity. Benzimidazol-2-ylidene gold(I) complexes are thioredoxin reductase inhibitors with multiple antitumor properties Gold(I)-mediated inhibition of protein tyrosine phosphatases: a detailed in vitro and cellular study Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs). Ligand effects in homogeneous Au catalysis Stable cyclic carbenes and related species beyond diaminocarbenes Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes. Gold-catalyzed [4C+3C] intramolecular cycloaddition of allenedienes: synthetic potential and mechanistic implications Carbene complexes of gold: preparation, medical application and bonding N-heterocyclic carbene gold(I) and copper(I) complexes in C-H bond activation. Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes Cyclic (Alkyl)(amino)carbene Gold(I) complexes: A Synthetic and Structural Investigation. Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts NHC gold halide complexes derived from 4,5-diarylimidazoles: synthesis, structural analysis, and pharmacological investigations as potential antitumor agents Cytotoxicity of gold(I) N-heterocyclic carbene complexes assessed by using human tumor cell lines Hyperconjugation Homogeneous catalytic hydroamination of alkynes and allenes with ammonia Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives Gold-catalyzed hydroamination of alkynes and allenes with parent hydrazine A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene A cationic gold(I) complex as a general catalyst for the intermolecular hydroamination of alkynes: application to the one-pot synthesis of allenes from two alkynes and a sacrificial amine Concomitant formation of N-heterocyclic carbene-copper complexes within a supramolecular network in the self-assembly of imidazolium dicarboxylate with metal ions. Ynamides: stable ligand equivalents of unstable oxazol-4-ylidenes (novel mesoionic carbenes). Liquid crystals of gold(I) N-heterocyclic carbene complexes Theoretical investigations of β-trimethylsilyl-substituted iminium ions
author name string	wds:Q57006669-50CA113B-DC7F-4974-B5A2-72EFE88F95DC wds:Q57006669-8A7F7104-ECF8-402C-AD8F-5A1083E51743 wds:Q57006669-F8D716DC-588C-4E87-B13B-23AF9E90D286
author name string	Patricia Pérez-Galán Annamalai Murali Filip Kolundžić
rdfs:label	A Cyclization-Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold(I)-Aminocarbene Complexes (en) A Cyclization-Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold (nl)
skos:prefLabel	A Cyclization-Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold(I)-Aminocarbene Complexes (en) A Cyclization-Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold (nl)
name	A Cyclization-Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold(I)-Aminocarbene Complexes (en) A Cyclization-Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold (nl)
author	wds:Q57006669-3CF1D055-40E6-487C-B595-9056E179E716 wds:Q57006669-62340B68-65B9-42D8-944A-1F2AC04B1D6A wds:Q57006669-8F87DED7-CF2B-4472-A940-002A465C24D0 wds:Q57006669-C874D7F5-B409-4732-AA3E-F9CADB04D01B
author	Carsten Strohmann Herbert Waldmann Kamal Kumar Jonathan O Bauer
title	wds:Q57006669-AD133063-863E-4191-9D24-99C20B830A3E
title	A cyclization-rearrangement cascade for the synthesis of structurally complex chiral gold(I)-aminocarbene complexes (en)
page(s)	wds:Q57006669-48F9FEFF-3C35-4D54-83D8-15A30F900B67
page(s)	8122-8126
instance of	wds:Q57006669-F3EAC8BC-CB1C-4C68-AFF5-E5520309A475
instance of	scholarly article
main subject	wds:Q57006669-4AFCB49F-C6AB-4C9B-B8A2-4738F72005A5

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