About: A Low-Spin Ruthenium(IV)-Oxo Complex: Does the Spin State Have an Impact on the Reactivity?

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scholarly article by Takahiko Kojima et al published 23 September 2010 in Angewandte Chemie International Edition

Attributes	Values
rdf:type	Item
description	wetenschappelijk artikel (nl) article scientifique publié en 2010 (fr) наукова стаття, опублікована у вересні 2010 (uk) im September 2010 veröffentlichter wissenschaftlicher Artikel (de) scholarly article by Takahiko Kojima et al published 23 September 2010 in Angewandte Chemie International Edition (en)
publication date	wds:Q58227407-08F623B5-568F-48AD-9C4F-9C8BA00AA593
publication date	2010-09-23 00:00:00Z (xsd:dateTime)
language of work or name	wds:Q58227407-0598423C-198A-4BBC-A2FA-706A89CFAFE5
language of work or name	English
cites work	wds:Q58227407-0044B46A-8A19-4C75-95A3-D8557FC7BBAC wds:Q58227407-02F747E1-FD32-4129-828E-C00669192EAE wds:Q58227407-07457ECA-6AEB-412F-8F17-54BE7CAD06F9 wds:Q58227407-1478CA8C-344C-4379-A22C-0154092A2E0F wds:Q58227407-16A18C34-815A-48F9-A77C-AB74A8FBF179 wds:Q58227407-182CFA70-08D1-4560-8AD7-098BDF88E08D wds:Q58227407-1C73442A-CDAC-4494-84B1-0AF16B61C064 wds:Q58227407-1FD11D20-CAB7-43C5-80F4-9F3F264A4132 wds:Q58227407-39DC806C-C6D0-4A0C-B83A-0CF502B015CE wds:Q58227407-4BC45A5B-82FF-4E46-8E52-3F2A7A768101 wds:Q58227407-5472502E-2749-419A-931D-DF39A315E854 wds:Q58227407-556DF87F-36CF-4047-B99C-B7A3A1707695 wds:Q58227407-5B868683-9BAB-4887-BC24-8008C03AE901 wds:Q58227407-66E0CE56-41CF-4A03-8483-65AE2E9330D1 wds:Q58227407-6BF3767D-C06C-4944-9455-C44298DB27CE wds:Q58227407-6F1C1BB3-EA27-41A6-B4AA-705F23A053B0 wds:Q58227407-70FF8D53-A217-4D70-9F2C-FDDC10770BF7 wds:Q58227407-7FEDAE96-23FC-48C5-B2D0-9C80B912446F wds:Q58227407-9C4F78BA-8954-45A5-BD37-021458A44FF0 wds:Q58227407-9CCE4786-DD32-410E-9CD6-2825180B2C44 wds:Q58227407-A42DFDA8-7A56-4D9E-9EF8-D863B18BB3B1 wds:Q58227407-C08B17BF-70AB-47F8-AE29-A50B7F6EE10F wds:Q58227407-C5309030-B901-44D2-9AC7-B1244A5411AB wds:Q58227407-CB35759E-4808-46B1-BFF8-B67307664A14 wds:Q58227407-DAD5C110-3279-4D9A-A335-CA19F1A067F8 wds:Q58227407-EC9D9109-A0F4-4621-A1B7-83B95004083C wds:Q58227407-F7985CBE-1DB2-4A39-8792-8E4479E21B5E wds:Q58227407-F93018CE-EA4E-4BC9-AB3A-5F712F167065 wds:Q58227407-F9A4E189-E134-44CA-8261-2A3FB50CF2B4
cites work	The bioinorganic chemistry of iron in oxygenases and supramolecular assemblies Proton-coupled electron transfer High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions Large ground-state entropy changes for hydrogen atom transfer reactions of iron complexes The remarkable reactivity of high oxidation state ruthenium and osmium polypyridyl complexes Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source. Water as an oxygen source in the generation of mononuclear nonheme iron(IV) oxo complexes. Mechanism of oxidation reactions catalyzed by cytochrome p450 enzymes. The catalytic pathway of horseradish peroxidase at high resolution Heme-Containing Oxygenases Reactivity of high-valent iron-oxo species in enzymes and synthetic reagents: a tale of many states Iron vs. ruthenium--a comparison of the stereoselectivity in catalytic olefin epoxidation. Catalytic Asymmetric Dihydroxylation Recent advances in transition metal catalyzed oxidation of organic substrates with molecular oxygen The road to non-heme oxoferryls and beyond Mechanistic insights into hydride-transfer and electron-transfer reactions by a manganese(IV)-oxo porphyrin complex Solvent effects on the oxidation of RuIV=O to O=RuVI=O by MnO4-. hydrogen-atom versus oxygen-atom transfer. Manganese Cluster in Photosynthesis: Where Plants Oxidize Water to Dioxygen An all-inorganic, stable, and highly active tetraruthenium homogeneous catalyst for water oxidation A two-state reactivity rationale for counterintuitive axial ligand effects on the C-H activation reactivity of nonheme FeIV=O oxidants What factors influence the ratio of C-H hydroxylation versus C=C epoxidation by a nonheme cytochrome P450 biomimetic? Propene activation by the oxo-iron active species of taurine/alpha-ketoglutarate dioxygenase (TauD) enzyme. How does the catalysis compare to heme-enzymes? Differences in and comparison of the catalytic properties of heme and non-heme enzymes with a central oxo-iron group. Nonradical mechanism for methane hydroxylation by iron-oxo complexes. Mechanistic insight into alcohol oxidation by high-valent iron-oxo complexes of heme and nonheme ligands A novel monooxoruthenium(V) complex containing a polydentate pyridyl amine ligand. Syntheses, reactivities, and x-ray crystal structure of [RuIII(N4O)(H2O)](ClO4)2 Model complexes for the cis-ruthenium(VI)-dioxo system. Novel chemistry of [RuIII(N4O)(OH2)][ClO4]2 (N4OH = bis[2-(2-pyridyl)ethyl][2-hydroxy-2-(2-pyridyl)ethyl]amine) Water oxidation: a robust all-inorganic catalyst Kinetics and mechanism of the oxidation of hydroquinones by a trans-dioxoruthenium(VI) complex
author name string	wds:Q58227407-79EB5217-809C-4A11-955A-E92EAADE388E wds:Q58227407-912CCB01-D490-424C-B334-E0D478B32B02 wds:Q58227407-DD79C951-758E-461A-AF68-AA4AA2A36C90 wds:Q58227407-E91A9C56-E263-4C64-98B7-64D937A552E9
author name string	Kazunari Yoshizawa Takashi Ogura Yuichirou Hirai Kenichiro Ikemura
rdfs:label	A Low-Spin Ruthenium(IV)-Oxo Complex: Does the Spin State Have an Impact on the Reactivity? (en) A Low-Spin Ruthenium (nl)
skos:prefLabel	A Low-Spin Ruthenium(IV)-Oxo Complex: Does the Spin State Have an Impact on the Reactivity? (en) A Low-Spin Ruthenium (nl)
name	A Low-Spin Ruthenium(IV)-Oxo Complex: Does the Spin State Have an Impact on the Reactivity? (en) A Low-Spin Ruthenium (nl)
author	wds:Q58227407-1AD52C78-0090-4C93-89B2-2164529FA643 wds:Q58227407-2403574C-404F-4727-9CEC-8DA27B1F5B79 wds:Q58227407-B8397C2D-560B-4257-BBC6-11EC4FDF7B08 wds:Q58227407-D966F757-AA5F-4F24-B2CE-42B12B13B6F1
author	Shunichi Fukuzumi Takahiko Kojima Yoshihito Shiota Tomoya Ishizuka
title	wds:Q58227407-2FE42D98-C684-4C99-A3C0-0630357FEAB5
title	A Low-Spin Ruthenium(IV)-Oxo Complex: Does the Spin State Have an Impact on the Reactivity? (en)
page(s)	wds:Q58227407-1AC2234E-D776-4F0E-B752-068E27D63CDC
page(s)	8449-8453
instance of	wds:Q58227407-B5BB487F-CC2F-42E0-8955-878F936E1A0D
instance of	scholarly article
main subject	wds:Q58227407-03283247-F09A-4AEF-81CE-E38A1D4CF7A1 wds:Q58227407-10A6D326-201C-4DDB-8354-E32FDF822FA0 wds:Q58227407-7AE68D4C-820A-484A-A93C-143E61F0C745
main subject	ruthenium

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