About: Rh-Catalyzed AldehydeAldehyde Cross-Aldol Reaction under Base-Free Conditions: In Situ Aldehyde-Derived Enolate Formation through Orthogonal Activation

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About: Rh-Catalyzed AldehydeAldehyde Cross-Aldol Reaction under Base-Free Conditions: In Situ Aldehyde-Derived Enolate Formation through Orthogonal Activation Goto Sponge NotDistinct Permalink

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description	article (en) wetenschappelijk artikel (nl) наукова стаття, опублікована у вересні 2013 (uk) im September 2013 veröffentlichter wissenschaftlicher Artikel (de)
publication date	wds:Q57740723-9153BCD4-1DC5-40B4-B257-50C9711EB5E3
publication date	2013-09-23 00:00:00Z (xsd:dateTime)
cites work	wds:Q57740723-003A6678-2A17-454B-83E3-F81FF55B6028 wds:Q57740723-0F7AB917-481B-4F14-8B3F-DB5E67BEEE5D wds:Q57740723-11D3357B-2D98-43E5-A73B-CB0E2EBAB3EC wds:Q57740723-1223CC83-40D3-4937-8BC0-68874F19C6E4 wds:Q57740723-1297D0F3-0FB5-428C-8811-8C2264CD54B1 wds:Q57740723-25A002A9-8A84-4774-8389-4754F5DBC15D wds:Q57740723-2602891D-2438-4488-B8A0-273C0B4B44D0 wds:Q57740723-28982442-77A3-4067-8684-F0C886AB3358 wds:Q57740723-391A4B7A-AFC2-4803-8AC7-507D32B6B2D5 wds:Q57740723-446CD851-6137-41FB-9D19-ADCD4398930B wds:Q57740723-44ACBD17-8678-4A56-B123-7C1057E91444 wds:Q57740723-48873EDE-E06F-4F49-ACE4-9FBC4C581D07 wds:Q57740723-55526C4E-6F47-4FAB-A2BD-90CC26B4EDA3 wds:Q57740723-5ACC08CE-2906-43D3-9E65-60150BBC2B5D wds:Q57740723-69D82C4E-E851-4345-9984-5273AA1927BE wds:Q57740723-6AA422D0-DEAE-435B-88B8-DEFFF5C32F31 wds:Q57740723-7749CF07-D83A-46B8-96F0-43172C062C7F wds:Q57740723-7759479D-86E2-4377-834C-80FE35473CB5 wds:Q57740723-7A60D0EA-09FD-4E3A-B933-AF0CDA98D7A8 wds:Q57740723-833E3327-1A7E-4F72-A7C7-B90B7FC97C43 wds:Q57740723-87A9E60D-6DF9-4D62-BA82-923DC496A489 wds:Q57740723-8AD3D02A-85A1-40D0-ACDF-CAA7B3F87284 wds:Q57740723-989C1474-CE9B-42EB-B071-47B0D8E44A5C wds:Q57740723-9B5C8B4C-E9F4-42C2-93F8-BB6CD0D8BD7B wds:Q57740723-9BDEC647-0AE1-4301-BF80-A0BE2D554205 wds:Q57740723-9F67AD18-3BD5-43EA-B643-AEC7F190467D wds:Q57740723-D48C9629-F137-4031-926F-B40F702DAED3 wds:Q57740723-E257F911-6272-46AD-A7C8-B618DCD5457A wds:Q57740723-EC62AD52-F4A4-48D1-94CC-99426D35ED44 wds:Q57740723-ECD85FF2-A6AE-4650-90ED-CAF75EDECE60 wds:Q57740723-F2B7607B-0399-4E9D-9B30-FCA3FDFA57AB wds:Q57740723-F7CB06D0-E149-4170-87C0-4C5AD9EF1D36
cites work	Two-step synthesis of carbohydrates by selective aldol reactions Redox economy in organic synthesis The atom economy--a search for synthetic efficiency Proline-Catalyzed Direct Asymmetric Aldol Reactions New cross-aldol reactions. Reactions of silyl enol ethers with carbonyl compounds activated by titanium tetrachloride Chiral phosphoramide-catalyzed, enantioselective, directed cross-aldol reactions of aldehydes Ketone super silyl enol ethers in sequential reactions: diastereoselective generation of tertiary carbinols in one pot. “Super Silyl” Group for Diastereoselective Sequential Reactions: Access to Complex Chiral Architecture in One Pot Transition Metal Catalyzed Alkene and Alkyne Hydroacylation Tris(trimethylsilyl)silyl-governed aldehyde cross-aldol cascade reaction Synthesis at the molecular frontier Chiral primary-tertiary diamine-Brønsted acid salt catalyzed syn-selective cross-aldol reaction of aldehydes The first direct and enantioselective cross-aldol reaction of aldehydes Modern aldol methods for the total synthesis of polyketides The direct catalytic asymmetric aldol reaction The importance of iminium geometry control in enamine catalysis: identification of a new catalyst architecture for aldehyde-aldehyde couplings Amino acid catalyzed neogenesis of carbohydrates: a plausible ancient transformation A diarylprolinol in an asymmetric, catalytic, and direct crossed-aldol reaction of acetaldehyde Rapid, one-pot synthesis of β-siloxy-α-haloaldehydes. A designer axially chiral amino sulfonamide as an efficient organocatalyst for direct asymmetric anti-selective Mannich reactions and syn-selective cross-aldol reactions. Atom economy: aldol-type products by vanadium-catalyzed additions of propargyl alcohols and aldehydes Rapid total syntheses utilizing "supersilyl" chemistry A triple-aldol cascade reaction for the rapid assembly of polyketides Rapid and stereochemically flexible synthesis of polypropionates: super-silyl-governed aldol cascades Lewis base catalyzed enantioselective aldol addition of acetaldehyde-derived silyl enol ether to aldehydes Rhodium-Catalyzed Cross-Aldol Reaction: In Situ Aldehyde-Enolate Formation from Allyloxyboranes and Primary Allylic Alcohols Asymmetric histidine-catalyzed cross-aldol reactions of enolizable aldehydes: access to defined configured quaternary stereogenic centers Efficient synthesis of beta-hydroxy ketones from allylic alcohols by catalytic formation of ruthenium enolates Acyclic stereoselection. 7. Stereoselective synthesis of 2-alkyl-3-hydroxy carbonyl compounds by aldol condensation Iridium-catalyzed 1,3-hydrogen shift/chlorination of allylic alcohols From allylic alcohols to aldols through a new nickel-mediated tandem reaction: synthetic and mechanistic studies. Rhodium-Catalyzed Cross-Aldol Reaction: In Situ Aldehyde-Enolate Formation from Allyloxyboranes and Primary Allylic Alcohols
author name string	wds:Q57740723-548CC47F-20DC-48AA-9B64-E7A560339A33
author name string	Motomu Kanai
rdfs:label	Rh-Catalyzed AldehydeAldehyde Cross-Aldol Reaction under Base-Free Conditions: In Situ Aldehyde-Derived Enolate Formation through Orthogonal Activation (en) Rh-Catalyzed AldehydeAldehyde Cross-Aldol Reaction under Base-Free Conditions: In Situ Aldehyde-Derived Enolate Formation through Orthogonal Activation (nl)
skos:prefLabel	Rh-Catalyzed AldehydeAldehyde Cross-Aldol Reaction under Base-Free Conditions: In Situ Aldehyde-Derived Enolate Formation through Orthogonal Activation (en) Rh-Catalyzed AldehydeAldehyde Cross-Aldol Reaction under Base-Free Conditions: In Situ Aldehyde-Derived Enolate Formation through Orthogonal Activation (nl)
name	Rh-Catalyzed AldehydeAldehyde Cross-Aldol Reaction under Base-Free Conditions: In Situ Aldehyde-Derived Enolate Formation through Orthogonal Activation (en) Rh-Catalyzed AldehydeAldehyde Cross-Aldol Reaction under Base-Free Conditions: In Situ Aldehyde-Derived Enolate Formation through Orthogonal Activation (nl)
author	wds:Q57740723-098C4854-05C2-40EB-AA1B-FA9A8D75C754 wds:Q57740723-4877FCC2-DA25-41A8-AA31-8216F94D0922 wds:Q57740723-A8A21914-6C39-4F62-AA67-4DD1A9070797
author	Kumiko Yamamoto Shigeki Matsunaga Luqing Lin
title	wds:Q57740723-480157AA-402A-4C9F-8300-150FFA97794C
title	Rh-catalyzed aldehyde-aldehyde cross-aldol reaction under base-free conditions: in situ aldehyde-derived enolate formation through orthogonal activation (en)
page(s)	wds:Q57740723-4B2E2C45-8224-4729-B40A-7F65D6EEFF26
page(s)	2974-2983
instance of	wds:Q57740723-596D12FE-29E8-4310-A8C3-490DBA4403F8
instance of	scholarly article
main subject	wds:Q57740723-F5B9B68A-0219-4B12-AE3C-AFB770F169D7
main subject	general chemistry
PubMed ID	wds:Q57740723-1B4A632B-C3F0-4136-B1ED-C8D93B70081C
PubMed ID	http://rdf.ncbi.nlm.nih.gov/pubchem/reference/24108498
PubMed ID	24108498
published in	wds:Q57740723-5A5D2F8B-B161-4DAC-8CCF-DF041B187792
published in	Chemistry - An Asian Journal
issue	wds:Q57740723-6812D722-D076-4D31-9AE5-CE8A05D41129
volume	wds:Q57740723-9175E5A4-CB9F-4477-950B-87EAAEB1C1C5

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