About: Generation and reactivity of sterically hindered iridium carbenes. Competitive α- vs. β-hydrogen elimination in iridium(iii) alkyls

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About: Generation and reactivity of sterically hindered iridium carbenes. Competitive α- vs. β-hydrogen elimination in iridium(iii) alkyls Goto Sponge NotDistinct Permalink

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scholarly article by Ernesto Carmona Guzmán et al published 2003 in Dalton Transactions

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rdf:type	Item
description	wetenschappelijk artikel (nl) наукова стаття, опублікована у 2003 (uk) article scientifique publié en 2003 (fr) im Januar 2003 veröffentlichter wissenschaftlicher Artikel (de) scholarly article by Ernesto Carmona Guzmán et al published 2003 in Dalton Transactions (en)
publication date	wds:Q57405202-0EB4BE73-4125-42FB-A2C1-EEFA5B29BAB3
publication date	2003-01-01 00:00:00Z (xsd:dateTime)
language of work or name	wds:Q57405202-CC1A13CD-3005-45E0-A5BB-DAE7EAC1764C
language of work or name	English
cites work	wds:Q57405202-11644B3C-C710-42E2-AF8E-1BA4912E2FC8 wds:Q57405202-23F39E1F-1DB3-4230-9898-3197FD4E2B94 wds:Q57405202-2817A557-69EA-47ED-9D81-D2439937D95D wds:Q57405202-2C08E742-0658-435A-87D9-488D150C4E1B wds:Q57405202-3035DDFF-5D45-4520-B5AB-2ACE135B27D8 wds:Q57405202-3B22AF66-9BBB-40DC-AA9E-B9B501765650 wds:Q57405202-4ED47205-0A65-4E65-BC48-89DBE7067DB1 wds:Q57405202-587881B0-C90C-4469-9D38-7A35257A648F wds:Q57405202-67FCEB97-8B97-494F-A5BC-2F0F6DC9A3E1 wds:Q57405202-69BB170D-0A4C-421F-BA48-0F386B0554BE wds:Q57405202-90F436ED-9B55-4BC5-B911-6A33DE406D75 wds:Q57405202-9ABB064A-1F16-45AD-B89E-C790C2EA8A83 wds:Q57405202-A2A42DBA-C48B-4FC7-BFC1-93D6CD26220F wds:Q57405202-A2D2C78F-3E30-4F7A-B761-557D578A33AD wds:Q57405202-B191C6E4-B898-474E-8C9F-51308C728655 wds:Q57405202-B8EB99BC-C6A4-4CF3-8E5D-D427CECC45B6 wds:Q57405202-DBE5A3C4-0DBC-4FA5-AE4C-744B86016AC5 wds:Q57405202-DEAA7748-5917-43F6-9A18-82530146E783 wds:Q57405202-F276CFD3-AF7C-4394-A77E-4434FAC1D13C wds:Q57405202-F4F1D74A-CE50-42AD-A2BF-041B479759EA wds:Q57405202-F7129268-DD5E-4DA3-85C6-CA640E5661C9 wds:Q57405202-FF347366-2D25-4B1F-9A59-FF8253C45FEF
cites work	High-oxidation-state molybdenum and tungsten alkylidyne complexes On the Existence of a Tungsten Carbonyl Carbene Complex Formation of Hydrido–η3-Allyl Complexes of IrIII by Sequential Olefinic CH Bond Activation and CC Coupling of Alkenyl and Olefin Ligands Geminal dehydrogenation of ether and amine C(sp3)H2 groups by electron-rich Ru(ii) and OsElectronic supplementary information (ESI) available: crystallographic data, fractional coordinates and isotropic thermal parameters, anisotropic thermal paramet Reaction of [P(2)N(2)]Ta==CH(2)(Me) with ethylene: synthesis of [P(2)N(2)]Ta(C(2)H(4))Et, a neutral species with a beta-agostic ethyl group in equilibrium with an alpha-agostic ethyl group ([P(2)N(2)] = PhP(CH(2)SiMe(2)CH(2))(2)PPh). Unprecedented pentadenticity of the HB(3-Phpz)3 (= TpPh) ligand Double carbon-hydrogen activation at the .alpha.-carbon of cyclic ethers by Tp*Ir(C2H4)2 C−H Bond Activation of Benzene and Cyclic Ethers by TpIrIII Species C–H bond activation reactions by TpMe2Ir(iii) centres. Generation of Fischer-type carbenes and development of a catalytic system for H/D exchange Unifying the mechanisms for alkane dehydrogenation and alkene H/D exchange with [IrH2(O2CCF3)(PAr3)2]: the key role of CF3CO2 in the “sticky’' alkane route CC Bond-Forming Reactions of IrIII-Alkenyls and Nitriles or Aldehydes: Generation of Reactive Hydride- and Alkyl-Alkylidene Compounds and Observation of a Reversible 1,2-H Shift in Stable Hydride–IrIII Alkylidene Complexes Vinylic C−H Bond Activation and Hydrogenation Reactions of Tp‘Ir(C2H4)(L) Complexes Five-coordinate trispyrazolylborate dihydridosilyl platinum(IV) complexes Coordinated carbenes from electron-rich olefins on RuHCl(PPr3i)2 Structural characterization of an intermediate in arene C-H bond activation and measurement of the barrier to C-H oxidative addition: a platinum(II) eta(2)-benzene adduct Electronic Effects on the Stability of Isomeric Alkyl Transition Metal Compounds‡ Electrophilic Cationic Ethylidene Complexes of Ir(III). Comparative α-Migratory Insertion Processes into Hydride and Ethyl Groups Equilibria between alpha- and beta-agostic stabilized rotamers of secondary alkyl niobium complexes Comparing the isoelectronic complexes [RuTp(CH3CN)3]PF6 (Tp = hydridotris(pyrazolyl)borate) and Investigation of the C−H Activation Potential of [Hydrotris(1H-pyrazolato-κN1)borato(1−)]iridium (IrTpx) Fragments Featuring Aromatic Substituentsx at the 3-Position of the Pyrazole Rings, The Choice of the Precursor Synthesis of η2:σ2-Diene Complexes of Iridium(III) by the Reaction of η4:π2-Diene Iridium(I) Species with Lewis Bases Generation of Heteroatom-Substituted Carbene Complexes of Iridium by Double C-H Activation of Ether and Amine Substrates This work was supported by the "Fonds zur Förderung der wissenschaftlichen Forschung" with a Schrödinger Stipendium for C.S. (J1
rdfs:label	Generation and reactivity of sterically hindered iridium carbenes. Competitive α- vs. β-hydrogen elimination in iridium(iii) alkyls (en) Generation and reactivity of sterically hindered iridium carbenes. Competitive α- vs. β-hydrogen elimination in iridium (nl)
skos:prefLabel	Generation and reactivity of sterically hindered iridium carbenes. Competitive α- vs. β-hydrogen elimination in iridium(iii) alkyls (en) Generation and reactivity of sterically hindered iridium carbenes. Competitive α- vs. β-hydrogen elimination in iridium (nl)
name	Generation and reactivity of sterically hindered iridium carbenes. Competitive α- vs. β-hydrogen elimination in iridium(iii) alkyls (en) Generation and reactivity of sterically hindered iridium carbenes. Competitive α- vs. β-hydrogen elimination in iridium (nl)
author	wds:Q57405202-7E41BAD6-0F00-45AE-A01F-66C223278848 wds:Q57405202-94D4176B-998B-4949-9024-B84789E92D10 wds:Q57405202-9EB1702E-9ACF-4224-8370-872BB3F6FEBD
author	Margarita Peneque Sosa Manuel L. Poveda Ernesto Carmona Guzmán
title	wds:Q57405202-528D4DDF-1E3C-4CB9-88F6-ADA99FB432BF
title	Generation and reactivity of sterically hindered iridium carbenes. Competitive α- vs. β-hydrogen elimination in iridium(iii) alkyls (en)
page(s)	wds:Q57405202-3735A487-E779-4675-AB05-5D227B646A12
page(s)	4022-4029
instance of	wds:Q57405202-AB644D00-CF94-4DE3-A518-88A8C9FA7F80
instance of	scholarly article
main subject	wds:Q57405202-8cea9090-7d0e-4aaa-b3ca-d2091b805be5
main subject	iridium
published in	wds:Q57405202-2F0BDD37-18CA-4F85-9501-F852DA1713E3
published in	Dalton Transactions
issue	wds:Q57405202-26853219-1DD8-479E-A4C3-17C4C3AFF3D7
issue	21
DOI	wds:Q57405202-626F772C-BCEB-44AA-B5DF-4B2D771FA293
DOI	http://dx.doi.org/10.1039/B303710J
DOI	10.1039/B303710J
is about of	https://www.wikidata.org/wiki/Special:EntityData/Q57405202
is cites work of	Functionalization of 3-Iridacyclopentenes. Tautomerisation of 2-Substituted Pyridines to N-Heterocyclic Carbene Ligands Induced by the 16 e− Unsaturated [TpMe2IrIII(C6H5)2] Moiety The Synthesis of Iridabenzenes by the Coupling of Iridacyclopentadienes and Olefins Reversible Double CH Bond Activation of Linear and Cyclic Ethers To Form Iridium Carbenes Synthesis and Reactivity of Iridacycles Containing the TpMe2Ir Moiety β- and α-Hydride abstraction in Gold(I) alkyl complexes Iridium(iii) complexes with polypyridine ligands coordinated as N-heterocyclic carbenes. Synthesis, structure and photophysical properties Iridium solutes effect C-H bond activation and C-C bond forming reactions of C6H6-MeOCH2CH2OMe solvent mixtures
is cites work of	wds:Q47890181-2491CB38-32CC-4D3A-9C8E-9B54118808B9 wds:Q57405150-0F447CF6-1AEE-4D71-A05F-58A76EEC9CD0 wds:Q57405145-8C0573C8-D360-4986-838B-1AB8C13A3055 wds:Q43723599-4EB53775-AF8A-4D0E-8495-C5EA806A0CB9 wds:Q57405148-DE46CCD2-0C9A-400A-9DA4-6073540932AD wds:Q57405185-44BF0C81-E147-470C-8408-AC56C2E19719 wds:Q60668751-0D3E4370-6CAF-4BB6-B9DF-ED3F9347EC80 wds:Q45015374-4E9FE2E3-9820-4420-9074-5B60E54A590C

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