About: Multiple Reaction Pathways in Rhodium-Catalyzed Hydrosilylations of Ketones

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scientific article published on 01 November 2009

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rdf:type	Item
description	wetenschappelijk artikel (nl) bài báo khoa học (vi) наукова стаття, опублікована в жовтні 2009 (uk) im Oktober 2009 veröffentlichter wissenschaftlicher Artikel (de) artículu científicu espublizáu en payares de 2009 (ast) scientific article published on 01 November 2009 (en)
publication date	wds:Q57397443-2F8C73F4-991D-4B13-A140-190A9AD9CFAB
publication date	2009-11-01 00:00:00Z (xsd:dateTime)
language of work or name	wds:Q57397443-39D7943F-975B-427F-BC89-13C597618454
language of work or name	English
cites work	wds:Q57397443-0051326E-C168-4DF7-90E1-7991B021EDC6 wds:Q57397443-0171A40F-1ECF-449B-BA44-2E23CD2F003B wds:Q57397443-0D1A34B4-8868-417C-BB96-5B7AEC15FA73 wds:Q57397443-220FA178-CAE9-4DCE-B669-B7F63E664A6D wds:Q57397443-27C4C0BD-DBDB-44F6-9057-78A637D5C7EB wds:Q57397443-2BFA5BB0-9B08-4C86-9340-AD2C3770B213 wds:Q57397443-2E5F12DA-FB59-4A2E-B9E0-9E0D41E7B97C wds:Q57397443-3014241F-867B-4EDE-9AC7-D13D8A790A0F wds:Q57397443-57E243F1-C482-489B-9C31-03683FC6A1A5 wds:Q57397443-5B4DDF78-4556-41DA-AA91-AEBA09024206 wds:Q57397443-6983E39D-1279-4D48-B3F2-049F47B6CB72 wds:Q57397443-69F073A5-541D-40EF-8E8F-6BDEA1C82F0F wds:Q57397443-6B8D56EC-D410-46C3-813E-C7F9D8AC5B3A wds:Q57397443-73B1A3BF-E58C-466F-BD4A-942E01BF57C2 wds:Q57397443-8BC8B3CA-FB97-4F4E-9F02-8EDA0DB79E7B wds:Q57397443-8DF09FBE-39E6-4E23-926D-09E734FFF7B0 wds:Q57397443-8E33FB8B-6E18-4A6C-8508-5EBCDEC4C020 wds:Q57397443-8F656016-5B01-4F5D-9E35-63C35C9F13A4 wds:Q57397443-A80CB402-8DD7-4913-93AF-310AA55A44EE wds:Q57397443-A8846FE7-097E-49A1-B7C6-1FB011811AFB wds:Q57397443-C7C388F9-3338-4E83-947A-CCB4A6448907 wds:Q57397443-CCD9B516-333C-4AC8-9391-C573E7A5760C wds:Q57397443-CD6E7478-ABD5-4DFE-903C-A4D4C73618FD wds:Q57397443-DA4BC315-D258-46CD-B601-F2EF244B58AC wds:Q57397443-E0A6F99B-E99A-421C-A8AC-C72FCD0A865E wds:Q57397443-E7BBBE83-6953-4254-9E48-E9F9EEA9E678 wds:Q57397443-FF99A423-ECD1-41B3-A214-F84AEF1243B0
cites work	Application of a new family of P,N ligands to the highly enantioselective hydrosilylation of aryl alkyl and dialkyl ketones Theoretical Studies of Some Transition-Metal-Mediated Reactions of Industrial and Synthetic Importance. Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density Density-functional thermochemistry. III. The role of exact exchange COSMO: a new approach to dielectric screening in solvents with explicit expressions for the screening energy and its gradient Density-functional exchange-energy approximation with correct asymptotic behavior Electronic structure calculations on workstation computers: The program system turbomole Density-functional approximation for the correlation energy of the inhomogeneous electron gas Highly enantioselective hydrosilylation of ketones with chiral and C2-symmetrical bis(oxazolinyl)pyridine-rhodium catalysts Synthetic development and chemical reactivity of transition-metal silylene complexes An efficient implementation of second analytical derivatives for density functional methods Application of chiral mixed phosphorus/sulfur ligands to enantioselective rhodium-catalyzed dehydroamino acid hydrogenation and ketone hydrosilylation processes Nuclear second analytical derivative calculations using auxiliary basis set expansions Ag+ -assisted hydrosilylation: complementary behavior of Rh and Ir catalysts (reversal of enantioselectivity). Metal Silylenes Generated by Double Silicon-Hydrogen Activation: Key Intermediates in the Rhodium-Catalyzed Hydrosilylation of Ketones Silyl, Hydrido-Silylene, or Other Bonding Modes: Some Unusual Structures of [(dhpe)Pt(SiHR2)]+(dhpe = H2PCH2CH2PH2; R = H, Me, SiH3, Cl, OMe, NMe2) and [(dhpe)Pt(SiR3)]+(R = Me, Cl) from DFT Calculations Designing the "search pathway" in the development of a new class of highly efficient stereoselective hydrosilylation catalysts Synthesis of novel axially chiral Rh-NHC complexes derived from BINAM and application in the enantioselective hydrosilylation of methyl ketones Metal Silylenes Generated by Double Silicon-Hydrogen Activation: Key Intermediates in the Rhodium-Catalyzed Hydrosilylation of Ketones Alkene hydrosilation by a cationic hydrogen-substituted iridium silylene complex Hydrogen-substituted osmium silylene complexes: effect of charge localization on catalytic hydrosilation. Reactivity of rhodium-triflate complexes with diphenylsilane: evidence for silylene intermediacy in stoichiometric and catalytic reactions New catalysts for the asymmetric hydrosilylation of ketones discovered by mass spectrometry screening Reduction of carbonyl compounds via hydrosilylation High oxidation-state (formally d(0)) tungsten silylene complexes via double Si-H bond activation. Silylene hydride complexes of molybdenum with silicon-hydrogen interactions: neutron structure of (eta(5)-C(5)Me(5))(Me(2)PCH(2)CH(2)PMe(2))Mo(H)(SiEt(2)). Sterically congested tripodal phosphites: conformational analysis, solid-state polymorphism, metal complexation, and application to the asymmetric hydrosilation of ketones
author name string	wds:Q57397443-00C61D3B-85D7-4759-BB8A-B63B447744CD wds:Q57397443-3A2E3D55-E261-4D87-A82D-BAD4E6AEF62B wds:Q57397443-756453FA-6A3D-48D8-85A6-0078084CBDF6 wds:Q57397443-7D391F04-A3D9-413C-B2FA-9AEE6368E43C wds:Q57397443-C1CD63FA-E229-43BC-8E99-6EC1C3BDE8AA
author name string	Peter Hofmann Lutz H Gade Stéphane Bellemin-Laponnaz Christian Haferkemper Markus Finger
rdfs:label	Multiple Reaction Pathways in Rhodium-Catalyzed Hydrosilylations of Ketones (en) Multiple Reaction Pathways in Rhodium-Catalyzed Hydrosilylations of Ketones (nl)
skos:prefLabel	Multiple Reaction Pathways in Rhodium-Catalyzed Hydrosilylations of Ketones (en) Multiple Reaction Pathways in Rhodium-Catalyzed Hydrosilylations of Ketones (nl)
name	Multiple Reaction Pathways in Rhodium-Catalyzed Hydrosilylations of Ketones (en) Multiple Reaction Pathways in Rhodium-Catalyzed Hydrosilylations of Ketones (nl)
author	wds:Q57397443-782A10D4-F6B3-49F8-9449-621AC1778F0B
author	Nathanaelle Schneider
title	wds:Q57397443-A155C375-4730-40BD-97B0-9889B586A91D
title	Multiple reaction pathways in rhodium-catalyzed hydrosilylations of ketones (en)
page(s)	wds:Q57397443-C1450140-9172-4171-8CFB-42AE5AE6D3CC
page(s)	11515-11529
instance of	wds:Q57397443-86DCDE40-74A0-44D1-99F0-8A98CAA80A22
instance of	scholarly article
main subject	wds:Q57397443-D1C97376-D54F-42E0-9E96-725E432CC64B
main subject	rhodium
PubMed ID	wds:Q57397443-5A772E6C-8977-4831-A9C0-38AF64E3237F
PubMed ID	http://rdf.ncbi.nlm.nih.gov/pubchem/reference/19813237
PubMed ID	19813237
published in	wds:Q57397443-BEEB309E-6133-4D4F-B4C6-E77C4B504CD2
published in	Chemistry—A European Journal
issue	wds:Q57397443-E300B6EC-D0D9-4F70-A46E-C6864FE15192
volume	wds:Q57397443-02E6E827-EFEA-4AEB-B11E-EC7370689A6E
issue	43
volume	15

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